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A homogeneous binary catalyst system, n-Bu 4 NBr/n-Bu 3 N, was found to be active for the synthesis of dimethyl carbonate from styrene oxide (SO), methanol, and supercritical CO 2 . Under the optimized conditions, the dimethyl carbonate yield could reach 84% at SO conversion of 98%. Several parameters were studied, i.e. catalyst precursors, reaction time and temperature, methanol/epoxide...
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