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In this paper, a thin calcium phosphate layer was prepared on the surface of Ti40Zr10Cu36Pd14 bulk metallic glasses (BMGs). All samples were dipped in HNO3 aqueous solution and boiled in 1.2 mol·L−1 NaOH aqueous solution. After the two preliminary treatment steps, they were soaked in simulated body fluid (SBF) to form an apatite layer on the surface. After immersion for 12 days, a coating composed...
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