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In an effort to determine the active state of supported palladium for the direct formation of H2O2 from H2 and O2, the catalytic behavior of Pd0/SiO2, PdO/SiO2 and partially reduced PdO/SiO2 was determined. The results obtained in an ethanol slurry, with chloride ions and H2SO4 being present, showed that the PdO/SiO2 catalyst was almost completely inactive for the formation of H2O2 at 10 °C. The Pd...
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