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The development of catalytic reactions involving carbon–hydrogen bond cleavage is one of the most attractive research subjects in organic and organometallic chemistries. To date, a vast number of studies of C–H bonds cleavage using stoichiometric amounts of transition-metal complexes have appeared. In the last decade, a variety of catalytic reactions involving C–H bond cleavage have been reported...
Ruthenium-catalyzed carbonylation reactions are described. The purpose of this chapter is to show how ruthenium complexes as catalysts are important in the recent development of carbonylation reactions. This review does not present a complete, historical coverage of ruthenium-catalyzed carbonylation reactions, but presents the most significant developments of the last 10 years. The emphasis is on...
Ruthenium-catalyzed carbonylation reactions are described. The purpose of this chapter is to show how ruthenium complexes as catalysts are important in the recent development of carbonylation reactions. This review does not present a complete, historical coverage of ruthenium-catalyzed carbonylation reactions, but presents the most significant developments of the last 10 years. The emphasis is on...
The development of catalytic reactions involving carbon–hydrogen bond cleavage is one of the most attractive research subjects in organic and organometallic chemistries. To date, a vast number of studies of C–H bonds cleavage using stoichiometric amounts of transition-metal complexes have appeared. In the last decade, a variety of catalytic reactions involving C–H bond cleavage have been reported...
The regioselective carbonylation of unactivated C(sp 3 )–H bonds of aliphatic amides, using 2-pyridinylmethylamine as a directing group in conjunction with Ru 3 (CO) 12 as a catalyst is described. The presence of a 2-pyridinylmethylamine moiety in the amides is crucial for the success of the reaction. Although ethylene is not incorporated into the products, its presence is...
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