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The presence of water vapor and sulfur oxides in diesel engine exhaust leads to the formation of sulfuric acid (H2SO4), which severely impacts the performance of Pt/Pd based emissions aftertreatment catalysts. In this study, a microkinetic model is developed to investigate the reaction pathways of H2SO4 formation on Pt based diesel oxidation catalysts (DOCs). The microkinetic model consists of 14...
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