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The lateral diffusion constants of two water insoluble redox surfactants, 4-alkaneamide derivatives of 2,2,6,6-tetramethyl-1-piperidynyloxy radical (C n Tempo where n=14 or 18) were measured using 2D voltammetry with 500μm long line electrodes positioned in the plane of the air/water interface. In order to extend these measurements into a region of low surface concentrations, we first examined...
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