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In the case of 38 and 96 kHz ultrasonic vibrating electrode (USVE) voltammetry of chlorpromazine, the oxidation current increased considerably with ultrasonic power (amplitude). Movement of the first oxidation product, crimson coloured cation radical, and the streaming of liquid in the neighbourhood of the USVE, were visually observed in order to understand the mechanism of the promotive effects...
By vibrating a platinum electrode surface ultrasonically in the voltammetry of chlorpromazine (CPM), the removal of the oxidation product, CPM + , and the supply of the reactant, CPM, were well promoted and the analytical sensitivity was considerably enhanced. It was possible to detect CPM at concentrations down to 10 -5 M with this method. Reproducible linear relationships...
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