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The peculiar halide affinity for silver results in an extraordinary electrocatalytic activity for the reduction of halides (either glycosyl halides or, more generally, aryl and alkyl halides). The most striking features are: (a) a reduction potential shift in the positive direction of about 1000 mV with respect to glassy carbon and 500 mV with respect to mercury; (b) a cage effect, evidenced in previous...
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