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On a subnanometer scale, an only one‐atom difference in a metal cluster may cause significant transitions in the catalytic activity due to the electronic and geometric configurations. We now report the atomicity‐specific catalytic activity of platinum clusters with significantly small atomicity, especially below 20. The atomic coordination structure is completely different from that of the larger...
Clusterverbindungen Wegen der unterschiedlichen elektronischen und geometrischen Konfiguration beeinflusst die Zahl der Atome in einem subnanometergroßen Platincluster dessen katalytische Aktivität erheblich. In der Zuschrift auf S. 9948 ff. zeigen K. Yamamoto et al., dass Pt19 für die Sauerstoffreduktion der aktivste Katalysator ist.
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