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Compartmented Bienzyme Biocatalysts
Biomimetic mineralization and slow seed‐induced nucleation strategy enables the synthesis of compartmented bienzyme system based on core‐shell ZIF@ZIF in aqueous solution. Bienzyme can be accurately localized into the shell and core with uniform distribution. The optimization of pore structure and bienzyme positional assembly provides a guidance for preparing efficient...
For complex cascade biocatalysis, multienzyme compartmentalization helps to optimize substrate transport channels and promote the orderly and tunable progress of step reactions. Herein, a simple and general synthesis strategy is proposed for the construction of a multienzyme biocatalyst by compartmentalizing glucose oxidase and horseradish peroxidase (GOx and HRP) within core–shell zeolite imidazole...
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