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Taking advantage of the improved spectral and temporal resolution of high-frequency/high-field EPR at 95 GHz/3.4 T and 360 GHz/12.8 T, as compared to conventional X-band EPR (9.5 GHz/0.34 T), two classes of photosynthetic protein systems are characterized with respect to structure and dynamics: (i) Light-generated electron-transfer intermediates in reaction center proteins, for example from the Rb. sphaeroides...
Pulsed high-field/high-frequency electron paramagnetic resonance (EPR) spectroscopy is used to disentangle many kinds of different effects often obscured in continuous wave (cw) EPR spectra at lower magnetic fields/microwave frequencies. While the high magnetic field increases the resolution of Gtensors and of nuclear Larmor frequencies, the high frequencies allow for higher time resolution for molecular...
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