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We report on quantum transport measurements of a carbon nanotube (CNT) quantum dot that is functionalized with magnetic {Mn4} complexes. The coupling between the spin‐5/2 MnII ions within each {Mn4} complex is predominantly antiferromagnetic. Coulomb diamond measurements at T = 4 K reveal that the covalent attachment of the complexes to the CNT framework has only little influence on the carbon nanotube...
We present first results on the covalent chemical functionalization of single‐walled carbon nanotubes with polynuclear {Mn4} coordination complexes. Raman spectra prove that the reaction can only be achieved for tubes which have been oxidized to create carboxylic groups. HRTEM is used to show that the reaction can be carried out directly on a substrate as well. Analysis of the D/G intensity ratio...
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