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The thermolysis of 2,4,6-triazido-1,3,5-triazine (I), 2,4,6-triazidopyrimidine (II), and 2,4,6-triazidopyridine (III) and its products were studied by DSC, mass spectrometry, IR spectroscopy, and electron microscopy. The thermal transformations of I gave planar nets formed by polyconjugated C–N bonds arranged into bundle aggregates. The thermolysis product of III consists of low-molecular compounds...
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