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A highly efficient palladium‐catalyzed cascade metallo‐ene/metallo‐carbene coupling reaction was developed to produce 2,3‐dihydropyrrole derivatives in high yields. In this transformation, two new Csp3−Csp2 and Csp2−Csp2 bonds were constructed in one‐pot. The alkene was one of the most easily functionalized groups, making it possible for these molecules to be transformed into more complex molecules...
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