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A dual-responsive amphiphilic diblock copolymer, poly(styrene-co-1-(2-methacryloxyethoxy)-2-(2-pyridyl)benzimidazole)-block-Poly(N-isopropylacrylamide-co-3-biphenyl-3-phenyl-8-methacryloxy-3H-naphtho[2,1-b]pyran-co-4-methamino-9-allyl-1,8-naphthalimide), also denoted as P(St-co-PBI)-b-P(NIPAM-co-NP-co-MANI), was synthesized by reversible addition fragmentation chain transfer polymerization followed...
The photochromic materials of single-molecule naphthopyrans (NP) are first used as hydrophobic and light-responsive group to synthesize amphiphilic polymer with the poly(ethylene glycol) (PEG) via Click-Chemistry. Such an amphiphilic polymer can self-assemble to light-responsive micelles with NP-core and PEG-shell in aqueous solution, as are confirmed by dynamic light scattering and transmission electron...
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