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Herein we report a polymerase chain reaction (PCR)‐free electrochemiluminescence (ECL) approach that uses ECL nanoprobes for the determination of cancer cells with high sensitivity. The ECL nanoprobe consists of gold nanoparticles (AuNPs), linker DNA, and tris(2,2′‐bipyridyl)ruthenium (TBR)‐labeled signal DNA. The linker DNA and signal DNA were modified on the surface of the AuNPs through AuS bonds...
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