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Thiolate‐protected nanoclusters with different charge states usually show similar structure frameworks but different electronic configurations, which are proved to dramatically affect their properties such as magnetism, photoluminescence, and catalytic activity. Until now, few nanoclusters with alterable charge states have been reported and only some of them are structurally solved, limiting the in‐depth...
T cell based‐immunotherapy has been a powerful strategy to eradicate tumor cells in clinical trials. Effectively expanding the therapeutic T cells for clinical demand is still a challenge. Here, artificial antigen‐presenting scaffolds are created for T cell ex vivo expansion. The antigen‐presenting hybrid colloidal crystal clusters (HCCCs) with multiple stimuli are generated by internal encapsulation...
In article number 2007486, Liang Cheng, Chaoliang Tan, and co‐workers report the activation of the near infrared absorption of layered metal oxide nanomaterials via a simple lithium treatment‐induced structural engineering, making them promising as robust biodegradable nanoagents for photothermal cancer therapy in the second near infrared window.
Layered metal oxides including MoO3 and WO3 have been widely explored for biological applications owing to their excellent biocompatibility, low toxicity, and easy preparation. However, they normally exhibit weak or negligible near‐infrared (NIR) absorption and thus are inefficient for photo‐induced biomedical applications. Herein, the structural engineering of layered MoO3 and WO3 nanostructures...
Antimonene quantum dots (AMQDs) are attracting considerable attention due to their fascinating physicochemical properties. However, research on their semiconductor characteristics, especially the photoluminescence performance, is still in a preliminary stage and the experimental verification is scarcely reported, significantly restricting their further applications. Herein, the photoluminescence property...
In article number 1906432, Dan‐Hong Wang, Xian‐He Bu, and co‐workers present a novel design strategy aiming to form heteropoly blues confined in defected Zr‐metal–organic framework (MOF), which can expose more unsaturated metal sites to promote the catalytic activity by adding thiourea. Moreover, 1‐butyl 3‐methyl imidazolium phosphomolybdate blues are also confined in Zr‐MOF to obtain higher oxidative...
The Keggin‐type polyoxometalates (POMs) are effective catalysts for oxidative desulfurization (ODS) and confining these POMs in metal–organic frameworks (MOFs) is a promising strategy to improve their performances. Herein, postsynthetic modification of POMs confined in MOFs by adding thiourea creates more unsaturated metal sites as defects, promoting ODS catalytic activity. Additional modification...
Semiconducting nanowires offer many opportunities for electronic and optoelectronic device applications due to their unique geometries and physical properties. However, it is challenging to synthesize semiconducting nanowires directly on a SiO2/Si substrate due to lattice mismatch. Here, a catalysis‐free approach is developed to achieve direct synthesis of long and straight InSe nanowires on SiO2/Si...
In the present work, the exploration of photodetectors (PDs) based on CsPbI3 nanotubes are reported. The as‐prepared CsPbI3 nanotubes can be stable for more than 2 months under air conditions. It is found that, in comparison to the nanowires, nanobelts, and nanosheets, the nanotubes can be advantageous to be used as the functional units for PDs, which is mainly attributed to the enhanced light absorption...
Carbon monoxide (CO) therapy has emerged as a hot topic under exploration in the field of gas therapy as it shows the promise of treating various diseases. Due to the gaseous property and the high affinity for human hemoglobin, the main challenges of administrating medicinal CO are the lack of target selectivity as well as the toxic profile at relatively high concentrations. Although abundant CO releasing...
Solar‐driven evaporation is a promising way of using abundant solar energy for desalinating polluted water or seawater, which addresses the challenge of global fresh water scarcity. Cost‐effectiveness and durability are key factors for practical solar‐driven evaporation technology. The present cutting‐edge techniques mostly rely on costly and complex fabricated nanomaterials, such as metallic nanoparticles,...
Photodynamic therapy (PDT) and photothermal therapy (PTT) are two kinds of treatment for tumors. Herein, a new aggregation‐induced emission (AIE)gen (MeO‐TPE‐indo, MTi) is synthesized with a D–π–A conjugated structure. MTi, which has an electron donor and an acceptor on a tetraphenylethene (TPE) conjugated skeleton, can induce the effective generation of reactive oxygen species (ROS) for PDT. With...
Microcarriers with oxygen‐delivering capacity have attracted increasing interest in the field of tissue regeneration. Here, a kind of molybdenum disulfide quantum dots (MoS2 QDs) integrated responsive porous microcarriers with controllable oxygen‐delivering ability for wound healing is presented. The specific gelatin methacryloyl (GelMa) porous microcarriers are derived from inverse opal microparticles...
Developing an efficient electrocatalyst for the hydrogen evolution reaction (HER) working in both acidic and alkaline solutions is highly desirable, but still remains challenging. Here, PtxNi ultrathin nanowires (NWs) with tunable compositions (x = 1.42, 3.21, 5.67) are in situ grown on MXenes (Ti3C2 nanosheets), serving as electrocatalysts toward HER. Such PtxNi@Ti3C2 electrocatalysts exhibit excellent...
Supercapacitors are energy storage systems capable of fast charging and discharging, thus generating superior power density. Porous carbon with high surface area and tunable pore size represents a promising candidate to construct ultrafast supercapacitors; so far, most porous carbon–based electrodes can only be charged to a moderate current density (100–200 A g−1), also with significant capacitance...
Cu nanowires (CuNWs) are considered as a promising candidate to develop high performance metal aerogels, yet the construction of robust and stable 3D porous structures remains challenging which severely limits their practical applications. Here, graphene‐hybridized CuNW (CuNW@G) core–shell aerogels are fabricated by introducing a conformal polymeric coating and in situ transforming it into multilayered...
Multidrug resistance (MDR) remains one of the biggest obstacles in chemotherapy of tumor mainly due to P‐glycoprotein (P‐gp)‐mediated drug efflux. Here, a transformable chimeric peptide is designed to target and self‐assemble on cell membrane for encapsulating cells and overcoming tumor MDR. This chimeric peptide (C16‐K(TPE)‐GGGH‐GFLGK‐PEG8, denoted as CTGP) with cathepsin B‐responsive and cell membrane‐targeting...
Hydrogen generation via electrocatalytic water splitting holds great promise for future energy revolution. It is desirable to design abundant and efficient catalysts and achieve mechanistic understanding of hydrogen evolution reaction (HER). Here, this paper reports a strategy for improving HER performance of molybdenum disulfide (MoS2) via introducing gold nanoclusters as a cocatalyst. Compared to...
Tumor hypoxia severely limits the efficacy of traditional photodynamic therapy (PDT). Here, a liposome‐based nanoparticle (designated as LipoMB/CaO2) with O2 self‐sufficient property for dual‐stage light‐driven PDT is demonstrated to address this problem. Through a short time irradiation, 1O2 activated by the photosensitizer methylene blue (MB) can induce lipid peroxidation to break the liposome,...
Icosahedral, octahedral, and cubic Pd@Pt core–shell nanocrystals with two atomic Pt layers are epitaxially generated under thermodynamic control. Such icosahedra exhibit remarkably enhanced catalytic properties for oxygen reduction reaction compared to the octahedra and cubes as well as commercial Pt/C, which can be attributed to ligand and geometry effects, especially twin‐induced strain effect that...
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