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Visible‐light photocatalytic carboxylation with CO2 is highly important. However, it still remains challenging for reluctant substrates with low reduction potentials. Herein, we report a novel photocatalytic carboxylation of C−N bonds in cyclic amines with CO2 via consecutive photo‐induced electron transfer (ConPET). It is also the first photocatalytic reductive ring‐opening reaction of azetidines,...
Visible‐light photocatalytic carboxylation with CO2 is highly important. However, it still remains challenging for reluctant substrates with low reduction potentials. Herein, we report a novel photocatalytic carboxylation of C−N bonds in cyclic amines with CO2 via consecutive photo‐induced electron transfer (ConPET). It is also the first photocatalytic reductive ring‐opening reaction of azetidines,...
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