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Presented by CD1d protein, KRN7000, a potent synthetic α-galactosylceramide, is known to stimulate the iNKT cells to produce different bioactive cytokines. Six new KRN7000 analogues, in which the amide bond in KRN7000 is replaced with O, NH, or ester groups incorporating variation of the acyl chain, or possessing an additional four-atom linker between the galactose and phytosphingosine moiety, were...
Xenotransplantations from pig to human are rapidly rejected because of the interaction between α-Gal epitopes carried by the graft and natural antibodies (anti-Gal antibodies) present in the blood of the recipient. This paper describes a three-component one-pot synthesis of three α-Gal related oligosaccharides with minimal protecting group manipulations in a very short period of time.
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