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Liquid Fe35Cu35Si30 alloy has achieved the maximum undercooling of 328 K (0.24TL) with glass fluxing method, and it displayed triple solidification mechanisms. A critical undercooling of 24 K was determined for metastable liquid phase separation. At lower undercoolings, α-Fe phase was the primary phase and the solidification microstructure appeared as homogeneous well-defined dendrites. When the undercooling...
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