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Mikrowellenchemie. In ihrem Forschungsartikel (e202114340) berichten Hong Li, Xin Gao et al. über den Nachweis von mikrowelleninduzierten Hot Spots in flüssigen Lösungen mithilfe eines Fluoreszenzthermometers, das an mikrowellenabsorbierenden Kohlenstoffpartikeln angebracht ist.
Ein vollständiger Satz von 2‐Nitrobenzyl‐modifizierten reversiblen Terminatoren wurde entwickelt, die unter UV‐Bestrahlung natürliche Hydroxymethylnukleotide generieren. Die Kombination aus einer stereospezifischen (S)‐tert‐Butylgruppe R an der Benzylposition und einer 5‐OMe‐Gruppe R′ am 2‐Nitrobenzylring verstärkt die photochemische Spaltung deutlich. Für 7‐Desaza‐7‐hydroxymethyl‐2′‐desoxyguanosin...
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