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Cyclopolymerization of triallyl isocyanurate (TAIC) as compared with its isomer triallyl cyanurate (TAC) is discussed in terms of the nonterminal units effect caused by the sterically bulky isocyanurate side groups. Thus, the monomer concentration dependence of the initial residual unsaturation is not explained by considering an ordinary cyclopolymerization mechanism, although TAC polymerization obeyed...
To improve the toughness of silicone-modified epoxy resin, aramid-silicone block copolymer was used as a compatibilizer. Fine silicone phases could be uniformly and stably dispersed in epoxy matrix by the addition of the block copolymer grafted with epoxy oligomers. The architecture of the block copolymer, such as the silicone content of the block copolymer and the molecular weight of epoxy and silicone...
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