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Starch is sensitive to moisture and is weak to durability in the protection application to ancient relics. Therefore, two fluorosilicone‐modified starches are firstly prepared and evaluated for the protection of historic stones. The fluoro‐silicone copolymer grafted starch of P(VTMS/12FMA)‐g‐starch is synthesized by grafting copolymer of vinyltrimethoxysilane (VTMS) and dodecafluoroheptyl methacrylate...
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