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Doping main‐group elements has become a unique strategy to fine‐tune optoelectronic properties of organic π‐conjugated molecules. Herein, we report the first example of diazaphosphinine based polycyclic hydrocarbons (DP‐PAHs) via facile synthetic protocols. Synthesis of diazaphosphinine heterocycles harnesses mild and efficient P−N chemistry. The heterocycles readily undergo photocyclizations by using...
Doping main‐group elements has become a unique strategy to fine‐tune optoelectronic properties of organic π‐conjugated molecules. Herein, we report the first example of diazaphosphinine based polycyclic hydrocarbons (DP‐PAHs) via facile synthetic protocols. Synthesis of diazaphosphinine heterocycles harnesses mild and efficient P−N chemistry. The heterocycles readily undergo photocyclizations by using...