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A recently isolated bismonoglyceride of heptadecanedioic acid, which represents a novel type of natural monoglycerides (i.e., with two instead of only one glycerol unit in the molecular architecture), was synthesized in enantiopure forms using a chiral-pool based approach with the 17-carbon chain constructed from undec-10-enoic acid and oct-7-en-1-ol via a cross metathesis and the stereogenic centers...
Small specific rotation is one of the setbacks in the studies of 1 (or 3)-acyl-sn-glycerols, which makes assessment of the optical purity/establishment of the identity of new compounds difficult. Some unusually large data reported for 3-stearoyl-sn-glycerol in the literature suggested that use of low sample concentrations in recording optical rotations might alleviate the long-existing (though probably...
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