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Acidic light: The reaction of the pincer‐type cyclometalated platinum(II) complex [PtCl(η3‐N C N)] with an N‐heterocyclic carbene (NHC) led to the [Pt(η2‐N C N)(NHC)2]+ complex with a pendent pyridyl group, which can be protonated by a variety of acidic vapors. This protonation switches the solid‐state phosphorescence on (see graphic).
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