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Single‐atom metal catalysts (SACs) are used as sulfur cathode additives to promote battery performance, although the material selection and mechanism that govern the catalytic activity remain unclear. It is shown that d‐p orbital hybridization between the single‐atom metal and the sulfur species can be used as a descriptor for understanding the catalytic activity of SACs in Li–S batteries. Transition...
Lithium–Sulfur Batteries
A descriptor, the d–p hybridization state between singleatom metal catalysts (SACs) and sulfur species, to guide the design of SACs for Li–S batteries, is proposed by Shiyong Zhao, Qianfan Zhang, Guangmin Zhou, Hui‐Ming Cheng, and co‐workers in article number 2105947. The large‐sized and flexible 3D electrodes with optimized SACs achieve high specific energy with low catalyst...
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