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As the electronic packaging density continues to increase, flip chip or stacked packaging via bump bonding is gradually replacing traditional wire bonding and will become the mainstream packaging form in the future. For copper bumps, this new type of electronic interconnection has not yet been fixed by industry standards. Therefore, this paper has made a preliminary study on the reliability of this...
The copper substrates with different preferred orientations (200) and (220) were prepared and the interfacial reactions of the Cu(200)/Sn and Cu(220)/Sn diffusion couples were studied after annealing at 423K. The thickness and morphology of the intermetallic compounds were investigated. The appearance of the Cu3Sn was observed at Cu(220)/Sn interface after aged for 4 hours and then the thickness of...
The copper substrates with different preferred orientations (200) and (220) were prepared and the interfacial reactions of the Cu(200)/Sn and Cu(220)/Sn diffusion couples were studied after annealing at 423K. The thickness and morphology of the intermetallic compounds were investigated. The appearance of the Cu3Sn was observed at Cu(220)/Sn interface after aged for 4 hours and then the thickness of...
Microstructure evolutions of as-reflowed and aged electroplated Cu/Sn/Cu sandwich structure with 20 or 40μm Sn layer have been investigated. Cu3Sn was observed at lower side of Cu/Sn/Cu structure with 40μm Sn layer after isothermal aging treatment for 24 hours, as for that structure with 20μm Sn layer, Cu3Sn appeared after aging for 48 hours. Regardless of Sn volume, the thickness of the blanket Cu...
In this paper, the effect of Ni-W alloy barrier layer on copper pillar/Sn IMCs evolution has been investigated. Additive W weight content of Ni-W alloy ranged from 16 to 18 at. %. Controlled thickness of barrier layer was prepared on Cu substrate. Then, excessive matte Sn electroplated on as-deposited Ni-W layer. Ni-W had compact microstructure in state of FCC solid solution, which means it had good...
In response to lead-free requirements and market forces, pure tin finishes have been widely used as a Pb-free option for semiconductor lead frames and electrical connectors in the microelectronics industry. Pure tin finishes could easy have a discoloration during reflow process since the reflow temperature is as high as 260°C, which could lead to a reliability issue. In this work, matte tin was electroplated...
Electronic assembly technology is in the transition from traditional tin-lead to lead-free. In comparison with Sn-Pb solders, high melting point and poor wettability of the lead-free solders lead to great challenge to present electronic assembly technologies. Inert nitrogen atmosphere can both widen the process window of reflow and improve the mechanical reliability of solder joints. The focus of...
Low cost electrodeposited Sn3.5Ag solder bumps fabrication technology was developed for three-dimensional packaging applications. Effect of reflow time on interfacial reaction of electroplated Sn3.5Ag solder bumps with Cu under-bump metallization (UBM) was investigated. The microstructure of eutectic Sn3.5Ag is composed of β-Sn phase and Ag3Sn IMCs in the solder region. At the interface between solder...
The microstructual stability of Sn-8Zn-3Bi/Cu and Sn-8Zn-3Bi-0.3Cr/Cu joints has been investigated under 85 °C temperature and 85% humidity conditions as a function of exposure time. The evolution of interface and near surface cross-sectional microstructures during exposure has been examined. A continuous single layer of intermetallic compound (IMC, hereafter) appears in both of the two kinds of solders...
This work reports on the wetting behavior of electrolyte in fine pitch Cu/Sn bumping process by electroplating. Three methods containing adding complex wetting agent to electrolyte, plasma treatment to photo-resist and ultrasonic vibration were taken to improve the wettability between electrolyte and related materials. Contact angles of electrolyte containing different amount of complex wetting agent...
The interfacial reaction between OSP, electrolytic Ni/Au, and electroless Ni/Pd/Au surface finish and SnAgCu solder on BGA package were investigated. After multiple reflows, IMC morphology and composition is examined by SEM and EDX. Cu6Sn5 formed between LF35 and OSP finish, and Ag3Sn were found disperse in the solder. Both (Nix,Cu1-x)3Sn4 and (Cux,Ni1-x)6Sn5 were observed on interface of electrolytic...
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