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Continuous semihydrogenation of phenylacetylene over an amorphous Pd 81 Si 19 catalyst in supercritical CO 2 as a solvent has been studied. The amorphous alloy afforded high selectivity to styrene without catalyst modification, which is usually necessary for high selectivity in “Lindlar-type” hydrogenations. The application of the highly active glassy metal alloy combined with...
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