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The discovery of Kahne glycosylation forwards a big step in the carbohydrate chemistry. Despite an extensive series of studies, the precise mechanism of this powerful glycosylation is still not fully understood. To address these 30‐year puzzles, the far side of Kahne glycosylation is explored in this study. After a series of control and tracking experiments, a number of important intermediates including...
Tamiflu is currently the most effective drug for the treatment of influenza, but the insufficient supply and side‐effects of this drug demand urgent solutions. We present a practical synthesis of Tamiflu by using novel synthetic routes, cheap reagents, and the abundantly available starting material D‐glucal. The strategy features a Claisen rearrangement of hexose to obtain the cyclohexene backbone...
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