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The heterogeneous metal‐organic framework Bi‐BTC successfully catalyzed the synthesis of para‐xylene from bio‐based 2,5‐dimethylfuran and acrylic acid in a promising yield (92 %), under relatively mild conditions (160 °C, 10 bar), and with a low reaction‐energy barrier (47.3 kJ mol−1). The proposed reaction strategy also demonstrates a remarkable versatility for furan derivatives such as furan and...
Heterogenes Bi‐BTC katalysiert die Bildung von para‐Xylol aus biologisch basiertem 2,5‐Dimethylfuran und Acrylsäure in 92 % Ausbeute bei relativ milden Bedingungen (160 °C, 10 bar). Die Reaktionsstrategie ermöglicht eine bemerkenswerte Vielseitigkeit für Furanderivate wie Furan und 2‐Methylfuran, wie Kevin C.‐W. Wu et al. in ihrer Zuschrift auf S. 634 demonstrieren.
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