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We have traced the development of the Ni electronic structure with thickness variation on flat and nano-structured Cu(001) surfaces by means of photoemission spectroscopy. The binding energy of the Ni 2p 3/2 main peak and satellite peak is found to have shifted monotonically in the direction opposite to each other, with the increase of Ni coverage. The reduced binding energy of the thin film’s...
Cluster-size-dependent binding energy (BE) shifts of Ni 2p 3/2 spectra in Ni clusters with respect to bulk Ni metal have been studied as a function of Ni coverage on clean rutile TiO 2 (001) and TiO 2 (110) surfaces at room temperature. As a common method to distinguish initial and final state contributions to the core-level binding energy shifts in clusters, Auger parameter...
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