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The front cover picture illustrates the Strecker reaction of formaldehyde, primary amines and TMSCN. HCOOH and TBAF were used as cocatalysts and the TMSCN was used to work as both the cyanide source and protecting reagent. As a result, the side reactions were suppressed efficiently and a broad range of aromatic and aliphatic amines were efficiently monocyanomethylated. This work is dedicated to Shenyang...
A set of conditions for the Strecker reaction of formaldehyde, amines, and TMSCN that affords three‐component coupling adducts as the major products is reported. HCOOH and TBAF are used as cocatalysts and the TMSCN functions as both cyanide source and protecting reagent for amines. As a result, the side reactions were suppressed efficiently and a broad range of aromatic and aliphatic amines were mono‐cyanomethylated...
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