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Collagen‐based hydrogels have a significant impact on wound healing, but they suffer from structural instability and bacterial invasion in infected wounds. Here, electrospun nanofibers of esterified hyaluronan (HA‐Bn/T) are developed to immobilize the hydrophobic antibacterial drug tetracycline by π–π stacking interaction. Dopamine‐modified hyaluronan and HA‐Bn/T are employed simultaneously to stabilize...