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A multichromophoric ternary complex containing a zinc porphyrin, perylene diimide and a methanofullerene was constructed. The use of a sequential Stern-Volmer analysis was employed to demonstrate the formation of the ternary complex and the energetics of a charge-separated state through a multistep photoinduced electron transfer was investigated.
A supramolecular complex was formed between ruthenium porphyrins and pyridyl-functionalised carbon nanotubes, which were in turn covalently attached to a silicon surface. The surface was characterised by LDI-ToF-MS, UV-vis spectrophotometry and steady-state spectrofluorometric methods.
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