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It was found that tiopronin could strongly enhance the electrochemiluminescence of tris(2,2’-bipyridine) ruthenium(II) (Ru(bpy)32+) in alkaline solution on a bare Pt electrode, based on which a sensitive, simple and rapid method for the determination of tiopronin was established. Under the optimal conditions, the logarithm of ECL enhancement has a linear relationship with the logarithm of tiopronin...
Based on the strong electrochemiluminescence (ECL) reaction between thiamazole and tris(2,2′‐bipyridine)ruthenium(II) (Ru(bpy)32+), a sensitive, simple and rapid flow injection analysis method for the determination of thiamazole was developed. When a Pt working electrode was maintained at a potential of +1.50 V (vs Ag/AgCl) in pH 12.0 H3PO4–NaOH solution containing thiamazole and Ru(bpy)32+ at a flow...
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