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The ADDSYM routine in the program PLATON [Spek (2015). Acta Cryst. C71, 9–18] has helped researchers to avoid structures of (metal–)organic compounds being reported in an unnecessarily low symmetry space group. However, determination of the correct space group may get more complicated in cases of pseudosymmetric inorganic compounds. One example is NaVO2F2, which was reported [Crosnier‐Lopez et al....
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