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In the liquid Rb–Se mixture there exists a liquid–liquid phase separation (miscibility gap) in the Se-rich concentration region. In order to study how the local structure is associated with the occurrence of the miscibility gap, EXAFS and neutron diffraction measurements for liquid Se, Rb 10 Se 90 , Rb 15 Se 85 and Rb 20 Se 80 mixtures have been carried...
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