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In this paper, we present X-ray absorption near-edge structure (XANES) measurements of triorganophosphinechalcogenides at the phosphorus K-edge. Using the XANES spectra as fingerprints, we can analyse the influence of the local environment of the absorbing atom on the shape of the absorption spectra and the energy positions of the resonances. Effects caused by the first and by higher coordination...
The phosphorus oxide cage compounds P 4 O 6 and P 4 O 6 X (X = O, S, Se) were investigated by X-ray absorption near edge spectroscopy (XANES) and by calculations of inner-shell excited states using a recently developed method which combines density functional and single-excitation configuration interaction methods (DFT/SCI). For an interpretation of the shape and energy...
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