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ansa-η5-Monofluorenyl cyclohexanolato zirconium complex 3 was shown to be active for the polymerization of ethylene when activated with methylaluminoxane (MAO) at 5 bar. Up to a polymerization temperature of 40 °C, 3/MAO resulted in linear poly(ethylene)s with saturated chain ends. However, at polymerization temperatures of 60, 80, and 100 °C, a mixture of branched poly(ethylene)s, linear α-olefins...
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