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The asymmetric hydrogenation (AH) of 3H‐indoles represents an ideal approach to the synthesis of useful chiral indoline scaffolds. However, very few catalytic systems based on precious metals have been developed to realize this challenging reaction. Herein, we report a Mn‐catalyzed AH of 3H‐indoles with excellent yields and enantioselectivities. The kinetic resolution of racemic 3H‐indoles by AH was...
The asymmetric hydrogenation (AH) of 3H‐indoles represents an ideal approach to the synthesis of useful chiral indoline scaffolds. However, very few catalytic systems based on precious metals have been developed to realize this challenging reaction. Herein, we report a Mn‐catalyzed AH of 3H‐indoles with excellent yields and enantioselectivities. The kinetic resolution of racemic 3H‐indoles by AH was...