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Poly(n-alkyl acrylate)s can have side chains that crystallize independently of the main chain; side-chain length can thus be used as a tunable parameter to control the gas permeability of membranes. The gas permeation response of poly(n-alkyl acrylate) and poly(m-alkyl acrylate) blends as a function of temperature is reported for varying side-chain lengths, n and m, and blend composition in the semi-crystalline...
The phase behavior of blends of copolycarbonates containing 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexanone (TMC-PC) and bisphenol-A repeat units with its constituent homopolymers was determined using melt mixing, solution casting, and precipitation casting methods. Miscibility was observed for all combinations except for some involving the TMC-PC homopolymer. Phase behavior was assessed using...
The phase behavior of blends of copolycarbonates containing 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexanone and bisphenol-A repeat units with styrene/acrylonitrile copolymers (SAN) was examined by differential scanning calorimetry or time resolved light scattering. No combination of the copolycarbonates or SAN materials proved to be miscible. Some of the blends studied become cloudy upon heating,...
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