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In 2007 two of us defined the σ‐Complex Assisted Metathesis mechanism (Perutz and Sabo‐Etienne, Angew. Chem. Int. Ed. 2007, 46, 2578–2592), that is, the σ‐CAM concept. This new approach to reaction mechanisms brought together metathesis reactions involving the formation of a variety of metal–element bonds through partner‐interchange of σ‐bond complexes. The key concept that defines a σ‐CAM process...
In 2007 two of us defined the σ‐Complex Assisted Metathesis mechanism (Perutz and Sabo‐Etienne, Angew. Chem. Int. Ed. 2007, 46, 2578–2592), that is, the σ‐CAM concept. This new approach to reaction mechanisms brought together metathesis reactions involving the formation of a variety of metal–element bonds through partner‐interchange of σ‐bond complexes. The key concept that defines a σ‐CAM process...