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In this work the three binary phase diagrams LiF–ZrF 4 , BeF 2 –ZrF 4 and UF 4 –ZrF 4 were thermodynamically assessed. The three ternary phase diagrams LiF–BeF 2 –ZrF 4 , BeF 2 –ZrF 4 –UF 4 and LiF–ZrF 4 –UF 4 were approximated on the basis of binary data. A pseudo-ternary LiF–BeF 2 –ZrF 4 ...
In a previous paper the LiF–NaF–RbF–LaF 3 quaternary system has been described as one of the possible fuels for molten salt reactor application. In this work the LiF–KF, NaF–KF, RbF–KF, LaF 3 –KF, LiF–CsF, NaF–CsF, KF–CsF, RbF–CsF and CsF–LaF 3 binary systems are thermodynamically assessed in order to add the KF and CsF to this existing system. The modified quasi-chemical model...
Four ternary phase diagrams of the quaternary system LiF–NaF–RbF–LaF 3 were calculated from the data of LiF–NaF, LiF–RbF, LiF–LaF 3 , NaF–RbF, NaF–LaF 3 and RbF–LaF 3 binary phase diagrams using the Kohler symmetric and Kohler–Toop asymmetric approximation. Excess Gibbs parameters of all six mentioned binaries were optimized using the experimental results taken from...
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