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The H2-distributed feeding concept using Pd/Ag-based membranes and an Ru-based catalyst in a Packed Bed Membrane Reactor (H2-PBMR) for the synthesis of biofuels via the so-called Fischer–Tropsch Synthesis has been demonstrated. The most successful approach resulted when H2-poor syngas (H2/CO=1) typically obtained from the gasification of biomass was fed directly through the reaction chamber, i.e.,...
The effect of the addition of Cl to Ru/γ-Al2O3 catalysts for the Fischer–Tropsch synthesis has been investigated. A series of four catalysts containing 3wt.% of Ru supported on γ-Al2O3 and promoted with different amounts of chlorine (Cl/Ru atomic ratios of 0, 1, 5 and 10) has been prepared. The catalysts were tested in the Fischer Tropsch synthesis in a fixed bed reactor. The initial rates for the...
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