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Complexes of V(IV)O with N(4) ethyl and/or phenyl thiosemicarbazides have been prepared to study the role of substituents, on the two sides of thiosemicarbazide moiety, on the behavior of the complex formation. The study of ligands in solution reflected the dependence of their ionization values on the nature of the function groups neighboring the active sites. Two main (octahedral and square-pyramid)...
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