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We reply to the remarks by Láng and Horányi [G.G. Láng, G. Horányi, Electrochim. Acta (2006), doi:10.1016/j.electacta.2006.07.009] on the meaning of the notion of “electrosorption valency” used by Abou Hamad et al. [I. Abou Hamad, S.J. Mitchell, Th. Wandlowski, P.A. Rikvold, G. Brown, Electrochim. Acta 50 (2005) 5518]. It is concluded that, contrary to the assertion of Láng and Horányi, the magnitude...
We present Monte Carlo simulations using an equilibrium lattice-gas model for the electrosorption of Cl on Ag(1 0 0) single-crystal surfaces. Fitting the simulated isotherms to chronocoulometry experiments, we extract parameters such as the electrosorption valency γ and the next-nearest-neighbor lateral interaction energy ϕnnn. Both coverage-dependent and coverage-independent γ were previously studied,...
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