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An efficient synthetic method has been developed for the preparation of a new family of atropisomeric amino alcohols with 1‐phenylpyrrole backbone. The synthesis is based on the different reactivities of the two carboxylic groups in optically active 1‐[2‐carboxy‐6‐(trifluoromethyl)phenyl]‐1H‐pyrrole‐2‐carboxylic acid (1). The chemical structures of the key intermediates were confirmed by spectroscopic...
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