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Au nanoparticles (NPs) have been proven to be excellent glucose oxidase (GOx) mimics, which can catalyze the electrons transform pathway from glucose to oxygen. This study confirmed AuNPs can accelerate the reaction between [Ag(NH3)2]+ and glucose under alkaline conditions, which is also known as the Tollens′ reaction, and the possible mechanism was proposed. Here, [Ag(NH3)2]+ instead of O2 acted...