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A supramolecular electrode was made of stacked Co II (tetrabenzoporphyrin). The stack was held together by π–π interactions and the first layer of the porphyrin complex was anchored to the glassy carbon surface through the porphyrin’s 4-aminopyridine group. An electrode formed by Co II (tetrabenzoporphyrin) adsorbed on the glassy carbon surface was inactive towards the reduction of...
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